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复合电解液添加剂对充电接受能力和低温高倍率放电性能的影响研究张兴，张祖波“，夏诗息，史俊雷"，余萍，戴长松”（1.湖北骆驼蓄电池研究院有限公司，湖北襄阳441000； 2.哈尔滨工业大学化学与化工学院，黑龙江哈尔滨150001）
摘要：充电接受能力和低温高倍率放电性能是富液电池的关键性能指标。本文分别采用K型、 J型两种电解液添加剂并分别考察了其单独对富液单体电池充电接受能力和低温高倍率放电性能的影响趋势，并得到K+、J*的最佳添加浓度分别为0.1mol/L、0.2mol/L。最后按照K J"+的最佳浓度进行复配添加，发现：当二者在最佳滚度时进行复配添加，能提高负极的充电接受能力10%以上，-18℃低温高倍率放电性能提高3%。此外，本文还通过循环伏安扫描、阴
极化分别对含不同K"、严+离子浓度的电解液添加剂对负极铅电极的电化学行为进行了研完。关键词：富液电池；充电接受能力；低温；高倍率放电；复合电解液添加剂
中图分类号：TM912.1
文献标识码：B
文章编号：1006-0847(2015)03-109-06
Thestudyaboutinfluenceof compositeelectrolyteadditiveoncharge acceptanceandhighratedischargeperformanceundercoldconditions
sodoI(1. Hubei Camel Storage Battery Research Institute Co., Ltd., Xiangyang Hubei 441000)
2. School of Chemistrc and Engineering, Harbin Industrial University, Harbin Heilongjiang I50001, China Abstract: Charge acceptance and high rate discharge performance under cold conditions were crucial performance indicators for flooded lead-acid batteries. Two electrolyte additives (type K and type J ) were tested and analyzed in relation to their effects on the charge acceptance capability performance and high rate discharge performance under cold conditions in this paper, and the best ions concentration of K** and J respectively was 0.1 mol/L, 0.2 mol/L. Then the K* and J+ ions were added into the electrolyte following the best ions concentration respectively. The test results showed that the negative charge acceptance and high rate discharge performance at -18 'C were improved by 10 % and 3 % respectively. In addition, by cyclic voltammetry and cathodic polarization test, the electrochemical behaviors of lead cathode electrode in the electrolytes added different concentrations of K** and J+ ions werestudied in this paper
Key words: flooded lead-acid battery; charge acceptance; low temperature; high rate discharge: composite electrolyte additive
收稿日期：2014-11-21*通讯联系人
2015 No.3 Vo1.520g