试验研究
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从废铅膏中制备3BS及其电化学性能的研究
马成，舒月红"，方宇"，张慧"，陈红雨"”
（1.华南师范大学化学与环境学院，广东广州510006：
2.广东高校储能与动力电池产学研结合示范基地，广东广州510006
摘要：本文首先采用碳酸盐将废铬膏中的铬浸提出，然后通过低温焕烧得到PbO，得到的PbO再与H,SO，溶液通过水热反应得到3BS。浸出结果表明，碳酸钠对度铅膏其有较高的浸提效率，可达98.0%以上；XRD测试结果表明，低温焕烧可得到较为纯净的PbO，水热反应得到的3BS的纯度在99.0%以上；电池性能表明，由3BS制务的电池首次放电容量有明显的提高，50次循环后容量保持率在75%以上。
关键词：铅酸蓄电池；废铅膏；氧化铬；三碱式硫酸铅；低温竣烧；浸提；碳酸盐；脱硫
中图分类号：TM912.4
文献标识码：A
文章编号：1006-0847(2016)02-51-04
Thestudyofperformanceoflead-acidbatterywith3BSfrom
usedleadpaste
MA Cheng', SHU Yuehong', FANG Yu', ZHANG Hui', CHEN Hongyu'2*
(I. School of Chemistry and Evironment, South China Normal University, Guangzhou Guangdong 510006; 2. Production, Teaching & Research Demonstration Base of Guangdong University for Energ)
Storage and Power Battery, Guangzhou Guangdong 510006, China)
Abstract: In this paper carbonate was used to leach lead from used lead paste, PbO was obtained by calcinating lead carbonate at the low temperature, and 3BS was obtained by hydrothermal reaction of lead oxide and H,SO, solution. The leaching results showed that leaching efficiency can reach more than 98 % when sodium carbonate was used to leach lead from used lead paste. XRD indicated that the pure PbO was obtained by low temperature calcination, and the content of 3BS was more than 99 % by hydrothermal reaction. The battery performance showed that the initial discharge capacity of the battery prepared by 3BS was obviously improved, and the capacity retention rate of the 50 cycles was above 75 %.
Key words: lead-acid battery; used lead paste; lead oxide; tribasic lead sulfate; low temperature calcination; leaching; carbonate; desulfurization
0前言
铅酸蓄电池是目前世界上生产量最大、使用途径最广的一种电池，汽车、助动车、轨道交通车不
收稿日期：2015-09-29
基金项目：NSFC-广东联合重点基金项目(U1201234）*通讯联系人
间断电源均来自铅酸蓄电池。随着市场需求的不断扩大，我国已经成为全球最大的铅酸蓄电池市场
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