第43卷第9期 2013年9月
涂料工业
PAINTCOATINGSINDUSTRY
Vol.43No.9 Sep.2013
自交联含氟丙烯酸树脂的合成及其在涂料中的应用
张艳丽，安秋风·，于莹
（陕西科技大学教育部轻化工助剂化学与技术重点实验室，西安710021)
摘要：以过氧化苯甲酰（BPO)为引发剂，将甲基丙烯酸十二氟庚酯（C04）与丙烯酸丁酯（BA）、甲基丙烯酸甲酯（MMA）、对氯甲基苯乙烯（CMS）和丙烯酸羟丙酯（HPA）［m（G04）：m（BA）：m（MMA）：m（CMS)：m（HPA）=1.4:2.5:4:3.5:3)进行溶液聚合，分别用连续和间断滴加法制得了自交联含氟丙烯酸酯树脂。测试了涂膜的疏水性、硬度等性能：探讨了合成方法、烘烤工艺、稀释剂、纳米颗粒对涂膜性能的影响。结果表明：采用间断滴加法制得的树脂疏水性较好：该树脂的最佳成膜温度是150℃，成膜时间为15min；加人纳米Ti0，后.使用含有高沸点溶剂的混合稀释剂，涂膜的表面接触角可达119°。
关键词：自交联型；含氟丙烯酸树脂；对氯甲基苯乙烯
中图分类号：TQ630.7
文献标识码：A
文章编号：0253-4312（2013)09-0031-05
Synthesisof Self-CrosslinkedFluorinated
PolyacrylateResinandItsApplication inCoatings
ZhangYanli,AnQiufeng,YuYing
(Key Laboratory of Auxiliary Chemistry &Technologyfor Chemical Industry,Ministry of Education,Shaanxi University of Science&Technology,Xi'an 710021,China)
Abstract:Thetitle fluorinated polyacrylic resin was prepared by solution polymerization with dodecafluoroheptyl methacrylate ester(GO4),butyl acrylate(BA)，methyl methacrylate(MMA), chloromethyl styrene (CMS) and 2 -hydroxypropyl acrylate (HPA)(at a mass ra-tio of 1.4:2.5:4:3.5:3) and continuous and intermittent feeding methods respectively at benzoyl peroxide (BPO)as initiator. A coating was formulated with this resin. And the hydro phobicityhardness and other properties of the coating film were investigated.The influence of synthesis method, baking procedure, the diluent and nanoparticles on the film properties were discussed. The experiment results indicated that the resin prepared by intermittent feeding method was preferably hydrophobic. The best curing procedure of the resin was 150C/15 min.The contact angle of coating surface could be up to 119o when nano -TiO, and the mixed solvent containinghighboiling solvent were used.
KeyWords:self-crosslinking:fluoroalkyl polyacrylateresin:chloromethyl styrene
【基金项目】陕西省科技厅13115重大科技专项项目（2010ZDKG-35）：陕西省教育厅产业化培育项目（2011JG25）；陕西省轻化
工助制重点实验室项目（12JS017）
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