第1期
世成等：新型光催化材料探索和研究进展
Study on Photocatalytic Properties of AgMO, ( M = A1, Ga, In) : Effects of Chemical Compositions, Crystal Structures, and Electronie Struetures[J]. J Phys Chem C, 2009(113) : 1 560 1 566.
[28] Hara M, Hitoki G, Takata T, et al. TaON and Ta, Ns as New
Visible Light Driven Photocatalysts[J].
Catalysis Todey, 2003
(78) : 555 560.
[29] Kasahara A, Nukumizu K, Hitoki G, et al.
Photoreactions on
LaTiO, N under Visible Light Iradiation [ J]. J Phys Chem A, 2002(106) : 6 750 6 753.
[30] Yamasita D, Takata T, Hara M, et al. Recent Progress of Vis-
ible-Light-Driven Heterogeneous Photocatalysts for Overall Wster Splitting[ J]. Sofid State fonics, 2004( 172) : 591 ~ 595.
[31] Zong X, Yan H J, Wu G P, et al. Enhancement of Photocata-
lytie H, Evolution on CdS by Loading MoS, as Cocatalyst under Visible Light Irradiation [J]. J Am Chem Soc, 2008 ( 130 ) : 7 176 7 177.
[32] Yan H J, Yang J H, Ma C J, et al. Visible-Light-Driven Hy-
drogen Production with Extremely High Quantum Efficiency on Pt-PdS/CdS Photocatalyst[J]- Joumal of Catalysis, 2009 ( 266) : 165 168.
[33] Wang X C, Maeda K, Thomas A, et al. A Metal-Free Poly-
meric Photocatalyst for Hydrogen Production from Water under Visible Light[J]. Nat Mater, 2009(8) : 76 80.
[34] Chen X F, Zhang J S, Fu X Z, et al.Fe-g-C, N,-Catalyzed
Oxidation of Benzene to Phenol Using Hydrogen Peroxide and Vis ible Light[ J]. J Am Chem Soc, 2009 in press.
[35] Wang P, Huang B B,Qin X Y, et al.Ag@ AgCl;A Highly
Efficient and Stable Photocatalyst Active under Visible Light[ J] Angew Chem, 2008(120) : 8 049 8 051
[36] Wang P, Huang B B, Zhang X Y, et al.Highly Effieient Visi-
ble-Light Plasmonie Photocatalyst Ag@ AgBr[ J]. Chem Eur J, 2009(15) ; 1 821 1 824
[37] Sayama K, Yoshida R, Kusama H, et al.
Photocatalytic De-
9
composition of Water into H and O, by a Two-Step Photoexcits tion Reaction using a W03 Suspension Catalyst and an Fe3+/ Fe2+ Redox System[J]. Chem Phys lett, 1997 (277) : 387 391.
[38] Kato H, Hori M, Konta R, et al.
Construction of Z-Scheme
Type Heterogeneous Photocatalysis Systems for Water Splitting in-to H2 and O2 under Visible Light Irradiation [ J]. Chem Lett, 2004, 33(10) : 1 348 1 349.
Higashi M, Abe R, Takata T, et al.
Photocatalytic Overall
[39]
Water Splitting under Visible Light Using ATaO, N( A = Ca, Sr, Ba) and WO, in a IO3- /I- Shuttle Redox Mediated System[J]. Chem Mater, 2009(21) : 1543 1 549.
[40] Chen X B, Burda C. The Electronic Origin of the Visible-Light
Absorption Properties of C-, N- and S-Doped TiO, Nanomaterials[J]. J Am Chem Soc, 2008(130) ; 5 018 5 019.
[41] Chun W J, Ishikawa A, Fujisawa H, e al. Conduction and
Valence Band Positions of Ta, Os , TaON, and Ta, N, by UPS and Electrochemical Methods [J]. J Phys Chem B, 2003(107) : 1 798 1 803.
[42] Zhang J, Xu Q, Feng Z C, et al. Importance of the Relation-
ship between Surface Phases and Photocatalytie Activity of TiO[J]. 4ngere Chem In Ed, 2008(47) : 1 766 1 769.
[43] Yamakata A, Ishibashi T, Onishi H. Effects of Water Addition
on the Methanol Oxidation on P/TiO, Photocatalyst Studied by Time-Resolved Infrsred Absorption Spectroscopy [ J]. J Phys Chem B, 2003(107) : 9 820 9 823.
[44] Chen T, Feng Z C, Wu G P, et al.Mechanistie Studies of
Photocatalytic Reaction of Methanol for Hydrogen Production PV TiO, by in situ Fourier Transform IR and Time-Resolved IR Spec-troscopy[J]. J Phys Chem C, 2007(111) : 8 005 8 014. Yoshida M, Yamakata A, Takanabe K, et αl. ATR-SEIRAS
[45]
Investigation of the Femi Level of Pr Cocatalyst on a GaN Photo catalyst for Hydrogen Evolution under Imadiation [ J]. J Am Chem Soc, 2009 in press.
4
材料专家聚宁热议减排
44#
资源、能源和环境间题已成为当代人类社会面临的重大挑战，11月28日，“第十二届全国青年材料科学技术研讨会”在南京举办，如何减少能源消耗，降低二氧化碳排放成为与会材料专家和青年学者的热议话题。
随着石油资源的日趋短缺，低碳经济已成为各国未来竞争力的重要角逐领域，其中近年来兴起的生物材料将有望成为未来的“硅元素”。中国工程院院士、南京工业大学校长欧阳平凯告诉记者，现在人类是以石油为基础制备各种化学制品，产生的二氧化碳被大量排放到大气中；而以天然的方法合成二氧化碳的动植物正在成为研究对象，科学家希望以生物制造出人类所需的各种材料，秸秆、藻类、虾蟹壳等都是科学家研究的对象。据悉，美国科学家已经通过饲养油藻成功提取出生物柴油，并取代石油作为燃料和新材料。我国科学家也用“虾兵蟹将”的外壳制成新型多功能生物材料，如止血药、润眼液、神经导管等。
（来源：科技日报）