
霖忆巢
第3期
2010年6月
现代地质 CEOSCIENCE
南海北部天然气水合物钻探区烃类气体
成因类型研究
黄霞,祝有海,卢振权,王平康(中国地质科学院矿产资源研究所,北京100037)
Vol. 24Na.3 Jun.2010
摘要:南海北部天然气水合物钻探区水合物气、顶空气样品和沉积物样品烃类气体组分和甲烷同位素特征测试结果表明,气体样品中烃类气体以甲烷为主,含微量乙烷和丙烷,C/(C+C)值均大于或接近1000。甲烷的碳同位素值为-54.1%~=62.2%e,氢同位素值为-180%e~-255%e,属于微生物气或是以微生物气为主的混合气,甲烷由C0,还原生成,由原地提供或侧向运移面来。沉积物样品酸解分析显示多数样品甲烷丰度大于90%,含一定量的乙烷、丙烷及少量的丁烷,C,/(C,+C,)值均小于50。甲烷的碳同位素值为-29.8%e~-48.2%e,呈现典型的热解气特征,显示由深部运移而来。
关键词:南海北部;天然气水合物;气体成因类型
中图分类号:P744.4;P59
文献标志码:A
文章编号:10008527(2010)03057605
StudyonGeneticTypesofHydrocarbonGasesfromtheGasHydrate
DrillingArea,theNorthernSouthChina Sea HUANG Xia, ZHU You-hai, LU Zhen-quan, WANC Ping-kang(Intitule of Mineral Resources, Chinese Academy of Geological Sciences, Bejing100037, China)
Abstract: Gas composition and isotopes of gas hydrate, headspace gas and sediment samples from the gas hy-drale drilling area, the Northem South China Sea, are analysed. Results show that gas hydrate and headspace gas are nearly composed of methane with trace ethane and propane. Their ratios of C,/(C, + C,) are higher than or close to 1,000. 8"C, values range from 54. 1%e to 62. 2%e, and 8Dcn, values vary from 180%e to 255%e. Hence they are mainly bacterial or mixed with bacterial gases, derived from CO, reduction and pro-duced in situ or by side migration, Results of acid-degassed gases of sediment samples also indicate that meth-ane is mostly higher than 90% , with some ethane, propane and minor butane. The ratios of C,/ (C, + C,) are lower than 50 and C, values change from 29.8%e to 48.2%e. These features are indicative of typical thermogenic gases migrated up from the depth.
Key words: the Northem South China Sea; gas hydrate; genetic-types of gases
0引言
括为具有“北油南气、西气东油”和“北部陆架浅水区富油、西部陆架浅水区富气、南部陆坡深水区
富气为主”的规律及特点)。2007年4一6月,中
我国南海北部沉积盆地油气资源丰富,海底天然气渗漏发育,根据迄今所获油气勘探成果及
国地质调查局在南海北部陆坡神狐海城实施了天
油气地质综合研究,其油气运聚分布特征可以概
然气水合物钻探,取得了天然气水合物实物样品,
收稿日期:2010-03-16;改回日期:2010-05-10;责任编辑:楼亚儿。
基金项目:国家"973"项目(2009CB219501);中央级公益性科研院所基本科研业务费资助项月(K0909)。
作者简介:黄霞,女,助理研究员,博士,1982年出生,地质学专业,主要从事天然气水合物气体成因来源的研究工作。
Email; huangxia@ live, com